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Radiocarbon Dating of Calcined Bones

Insights from Combustion Experiments Under Natural Conditions

Bibliographic Data

ID9245012
AuthorsAntoine Zazzo (0000-0001-7608-2207), Jean-François Saliège, Matthieu Lebon (0000-0003-4970-1230), Sébastien Lepetz, C Moreau (0000-0002-2876-6476)
Year2012
Volume54
Issue3-4
Pages855-866
Publication date2012-01-01
Peer ReviewedYes
Open AccessYes
TypeARTICLE
VenueRadiocarbon (JOURNAL)
Journal identifiersISSN: 0033-8222 • E-ISSN: 1945-5755
PublisherCambridge University Press (CUP) (PUBLISHER)
DOI10.1017/s0033822200047500
OpenAlexW2100628469
LanguageEN
Citations received48
References cited25

Radiocarbon dating of the carbonate remaining in calcined bones is widely regarded as a viable alternative to date skeletal remains in situations where collagen is no longer present. However, anomalously low δ 13 C values measured in calcined bones prompted questions about the origin of the carbon used for dating. The goal of this study was to quantify the magnitude of carbon isotope exchange between bone carbonate and environmental CO 2 for bones calcined under natural conditions. Four archaeological bones ranging in age between the Neolithic and the Medieval period were combusted on a separate open fire for up to 4 hr and subsamples of calcined bones were taken every hour. All the bones experienced a significant increase in IRSF values and decrease in carbonate content and δ 13 C values. 14 C ages measured in the carbonate fraction of well-calcined bones indicate that 67 ± 3% to 91 ± 8% of the carbon present in bone carbonate was replaced by carbon from the atmosphere of combustion. This finding confirms previous results obtained under laboratory conditions and has serious implications for 14 C dating of calcined bones found in archaeological contexts. The 14 C age obtained on a calcined bone will only reflect the true age of the bone sample if the age difference between the bone and the charcoal can be neglected. Our results show also that δ 13 C values of calcined bones can be used to estimate the degree of C exchange and control for post-burial diagenetic alteration

Calcination · Carbon fibers · Carbonate · Charcoal · Combustion · Composite material · Diagenesis · Geochemistry · Isotopes of carbon · Metallurgy · Mineralogy · Radiocarbon dating · Total organic carbon · Archaeology and ancient environmental studies · Chemistry · Isotope Analysis in Ecology · Materials Science · Pleistocene-Era Hominins and Archaeology · Catalysis · Environmental Chemistry · Geology · Paleontology

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Unique citing works48
Citations per year3,43
Citation span2012 - 2026 (15)
Citation velocitycurrent
Highly citedNo
Citation typesNeutral: 42
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