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Non-Invasive Raman Analysis of 18th Century Chinese Export/Armorial Overglazed Porcelain

Identification of the Different Enameling Techniques

Bibliographic Data

ID13124656
AuthorsPhilippe Colomban (0000-0001-6099-5423, Sorbonne Université, corresponding author), Anh‐Tu Ngo (0000-0002-9225-6796, Centre National de la Recherche Scientifique), Nicolas Fournery
Year2022
Volume5
Issue1
Pages233-259
Publication date2022-01-23
Peer ReviewedYes
Open AccessYes
TypeARTICLE
VenueHeritage (JOURNAL)
Journal identifiersISSN: 2571-9408 • E-ISSN: 2571-9408
PublisherMDPI AG (PUBLISHER • IT)
DOI10.3390/heritage5010013
OpenAlexW4206922559
LanguageEN
Citations received4
References cited53

Six rare porcelains of the Qing Dynasty, in particular, dishes ordered respectively for Philibert Orry, the Duke of Penthièvre and a tureen from the service of Louis XV, with royal coat-of-arms, were analyzed non-invasively by Raman microspectrometry. A coffee pot with a rare decoration attributed to Cornelius Pronk was also analyzed as well as two plates, one decorated with an Imari-style pattern and the second post-decorated in the Low-Countries/Holland. The enamel types and coloring or opacifying agents were identified on the basis of combined Raman and SEM-EDXS analysis previously published as well as new section and surface analysis of five plate samples representative of different technologies (blue-and-white, Famille rose). The use of lead oxide for the preparation of overglaze is demonstrated. For the first time, the use of borax in the blue overglaze according to the recipe from the 1753 manuscripts of French chemist Jean Hellot is demonstrated on Chinese porcelain. This fact, like the use of cobalt free of manganese, demonstrates the use of European ingredients and/or recipes for ceramics exported from China to Europe. The highlighting of the use of different recipes or raw materials for porcelain from the same period can therefore be the signature of different workshops. For instance, three different Raman signatures of red decoration were identified from the hematite vibration modes: very narrow modes for Pronk’ coffee pot and Louis XV tureen, broad for Orry’ dish and intermediate for the others. Three workshops are thus expected. It is interesting to note that the use of arsenic for the realization of white enamels corresponds to the latest objects, made after 1738. China was therefore in the 18th century both an importer of European know-how, design and an exporter of enameled products made with imported technologies to Europe

Optics · Physics · Raman spectroscopy · Building materials and conservation · Conservation Techniques and Studies · Cultural Heritage Materials Analysis · Materials Science

  • Non-Invasive Identification of Blue-And-White Porcelain

    Open Access•Philippe Colomban, Gülsu Şimşek Franci et al.•Heritage•2026

  • Raman spectroscopy and Sers

    Open Access•Rosaceleste Zumpano, Federica Simonetti et al.•Journal of Cultural Heritage•2024

  • PXRF Data Evaluation Methodology for On-Site Analysis of Precious Artifacts

    Open Access•Philippe Colomban, Gülsu Şimşek Franci et al.•Heritage•2022

  • Non-Invasive Mobile Raman and pXRF Analysis of Armorial Porcelain with the Coat of Arms of Louis XV and Others Enamelled in Canton

    Open Access•Philippe Colomban, Gülsu Şimşek Franci et al.•Heritage•2024

  • Goods from the East, 1600–1800

    Open Access•Maxine Berg, Felicia Gottmann et al.•Goods from the East, 1600-1800•2015

  • Raman identification of natural red to yellow pigments

    Open Access•Françoise Froment, Aurélie Tournié et al.•Journal of Raman Spectroscopy•2008

  • A polychrome Mukozuke (1624–1644) porcelain offers a new hypothesis on the introduction of European enameling technology in Japan

    Open Access•Riccardo Montanari, Maria Francesca Alberghina et al.•Journal of Cultural Heritage•2018

  • Investigation of the Pigments and Glassy Matrix of Painted Enamelled Qing Dynasty Chinese Porcelains by Noninvasive On-Site Raman Microspectrometry

    Open Access•Philippe Colomban, Burcu Kırmızı et al.•Heritage•2020

  • Dorures des céramiques et tesselles anciennes

    Open Access•Philippe Colomban, Thomas Calligaro et al.•ArchéoSciences•2005

  • European cobalt sources identified in the production of Chinese famille rose porcelain

    Open Access•Rita Giannini, Ian C Freestone et al.•Journal of Archaeological Science•2017

  • Les porcelaines chinoises du palais de Santos

    Daisy Lion-Goldschmidt•Arts asiatiques•1984

  • The Origin of overglaze-blue enameling in Japan

    Open Access•Riccardo Montanari, Nobuyuki Murakami et al.•Journal of Cultural Heritage•2019

  • Microstructure, composition and processing of 15th century Vietnamese porcelains and celadons

    Open Access•Philippe Colomban, Nguyen Quang Liem et al.•Journal of Cultural Heritage•2003

  • Pigments and glassy matrix of the 17th-18th century enamelled French watches

    Open Access•Philippe Colomban, Burcu Kırmızı et al.•Journal of Cultural Heritage•2020

Unique citing works4
Citations per year1
Citation span2022 - 2026 (5)
Citation velocitycurrent
Highly citedNo
Citation typesNeutral: 3

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