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Enrichments of Cadmium and Arsenic and Their Effects on the Karst Forest Area

Bibliographic Data

ID15468707
AuthorsJinfeng Wang (0000-0002-6687-9420, Institute of Geochemistry), Xiaoyong Bai (0000-0001-9705-5574, Institute of Geochemistry), Fang Liu (0000-0002-7132-354X, Guizhou University, corresponding author), Jian Zhang (0000-0001-7681-8747, Guizhou University), Fei Chen (0000-0002-4500-2590, Institute of Geochemistry), Qian Lu (0000-0003-2226-9804, Institute of Geochemistry)
Year2019
Volume16
Issue23
Pages4665-4665
Publication date2019-11-22
Open AccessYes
TypeARTICLE
VenueInternational Journal of Environmental Research and Public Health (JOURNAL)
Journal identifiersISSN: 1661-7827 • E-ISSN: 1660-4601
PublisherMultidisciplinary Digital Publishing Institute (PUBLISHER • CH)
DOI10.3390/ijerph16234665
PMID31771125
OpenAlexW2991051835
LanguageEN
References cited32

An understanding of the enrichment mechanisms of cadmium (Cd) and arsenic (As) in the process of rock weathering and soil formation is essential to develop agriculture according to local conditions. However, the enrichments of soil Cd and As under natural background conditions in karst areas are still uncertain. The enrichment factor, geo-accumulation index, redundancy analysis, and other methods were used to analyze the enrichment degree and the influencing factors of Cd and As on 5 rock-soil profiles and 15 topsoil samples, which were collected from a karst forest area in Libo County, Guizhou Province. The results showed that the enrichment process was divided into three stages. In the first stage, Cd and As were enriched in carbonate rocks, and their mean concentrations were 1.65 and 3.9 times those of the corresponding abundance of the crust. In the second stage, the enrichment of the parent rock into the soil, the enrichment factors of Cd and As in the parent material horizon relative to the bedrock horizon were 9.2 and 2.82, respectively. The third stage refers to the enrichments of Cd and As in the topsoil, where Cd enrichment was more obvious than that of As. Soil organic matter (SOM) and phosphorus (P) are important factors that influenced the enrichments of Cd and As in the topsoil. The functional groups of SOM were complexed with Cd and As; P easily formed precipitates with Cd, and the tree litter was fed back to the topsoil, which may be the reason for the surface enrichment of Cd and As. This study will help the scientific community understand the enrichment mechanisms of soil Cd and As in karst areas

Arsenic · Bedrock · Cadmium · Geochemistry · Karst · Soil horizon · Soil water · Topsoil · Weathering · Arsenic contamination and mitigation · Chemistry · Environmental Science · Heavy Metal Exposure and Toxicity · Heavy metals in environment · Environmental Chemistry · Geology · Soil Science

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