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Qualitative Analysis of E-Liquid Emissions as a Function of Flavor Additives Using Two Aerosol Capture Methods

Bibliographic Data

ID15515599
AuthorsNathan C Eddingsaas (0000-0003-1539-5415, Rochester Institute of Technology), Todd Pagano (0000-0002-0298-7588, Rochester Institute of Technology), Cody Cummings (0000-0002-0742-0871, Rochester Institute of Technology), Irfan Rahman (0000-0003-2274-2454, University of Rochester Medicine), Risa Robinson (Rochester Institute of Technology), Edward Hensel (0000-0002-2682-0766, Rochester Institute of Technology, corresponding author)
Year2018
Volume15
Issue2
Pages323-323
Publication date2018-02-13
Open AccessYes
TypeARTICLE
VenueInternational Journal of Environmental Research and Public Health (JOURNAL)
Journal identifiersISSN: 1661-7827 • E-ISSN: 1660-4601
PublisherMultidisciplinary Digital Publishing Institute (PUBLISHER • CH)
DOI10.3390/ijerph15020323
PMID29438289
OpenAlexW2792247894
LanguageEN
Citations received3
References cited1

This work investigates emissions sampling methods employed for qualitative identification of compounds in e-liquids and their resultant aerosols to assess what capture methods may be sufficient to identify harmful and potentially harmful constituents present. Three popular e-liquid flavors (cinnamon, mango, vanilla) were analyzed using qualitative gas chromatography-mass spectrometry (GC-MS) in the un-puffed state. Each liquid was also machine-puffed under realistic-use flow rate conditions and emissions were captured using two techniques: filter pads and methanol impingers. GC-MS analysis was conducted on the emissions captured using both techniques from all three e-liquids. The e-liquid GC-MS analysis resulted in positive identification of 13 compounds from the cinnamon flavor e-liquid, 31 from mango, and 19 from vanilla, including a number of compounds observed in all e-liquid experiments. Nineteen compounds were observed in emissions which were not present in the un-puffed e-liquid. Qualitative GC-MS analysis of the emissions samples identify compounds observed in all three samples: e-liquid, impinge, and filter pads, and each subset thereof. A limited number of compounds were observed in emissions captured with impingers, but were not observed in emissions captured using filter pads; a larger number of compounds were observed on emissions collected from the filter pads, but not those captured with impingers. It is demonstrated that sampling methods have different sampling efficiencies and some compounds might be missed using only one method. It is recommended to investigate filter pads, impingers, thermal desorption tubes, and solvent extraction resins to establish robust sampling methods for emissions testing of e-cigarette emissions

Aerosol · Analytical Chemistry (journal · Chromatography · Desorption · Extraction (chemistry · Filter (signal processing · Flavor · Gas chromatography · Gas chromatography–mass spectrometry · Mass spectrometry · Methanol · Solvent · Thermal desorption · Advanced Chemical Sensor Technologies · Chemistry · Computer Science · Indoor Air Quality and Microbial Exposure · Smoking Behavior and Cessation · Organic Chemistry

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Citations per year0.5
Citation span2020 - 2021 (2)
Highly citedNo

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