Coordination Complexes of the Dimethylthiophosphonium Cation and Ligand Exchange

Bibliographic Data

ID23133549
AuthorsJan J Weigand (0000-0001-7323-7816, Department of Chemistry, Dalhousie University, Halifax, Nova Scotia B3H 4J3, Canada, and Department of Chemistry, University of New Brunswick, Fredericton, New Brunswick E3A 6E2, Canada), Behrooz Barjasteh Delforooz (corresponding author), Neil Burford (Department of Chemistry, Dalhousie University, Halifax, Nova Scotia B3H 4J3, Canada, and Department of Chemistry, University of New Brunswick, Fredericton, New Brunswick E3A 6E2, Canada), Devin Mahnke (Department of Chemistry, Dalhousie University, Halifax, Nova Scotia B3H 4J3, Canada, and Department of Chemistry, University of New Brunswick, Fredericton, New Brunswick E3A 6E2, Canada), Andreas Decken (Department of Chemistry, Dalhousie University, Halifax, Nova Scotia B3H 4J3, Canada, and Department of Chemistry, University of New Brunswick, Fredericton, New Brunswick E3A 6E2, Canada)
Year2007
Volume46
Issue19
Pages7689-7691
Publication date2007-09-01
Open AccessNo
TypeARTICLE
VenueInorganic Chemistry (JOURNAL)
Journal identifiersISSN: 0020-1669 • E-ISSN: 1520-510X
PublisherAmerican Chemical Society (ACS) (PUBLISHER)
DOI10.1021/ic7012792
PMID17705375
OpenAlexW17705375
LanguageEN
Citations received4
References cited14

The quantitative exchange of a 4-(dimethylamino)pyridine ligand on the dimethyl-thio-phosphonium cation by Me3P demonstrates the coordinative nature of the N-P and P-P bond and diversifies a fundamentally important new direction in the coordination chemistry of phosphorus as an acceptor.

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