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Multianalytical study of neapolitan yellow tuff rotting

Archaeological park of herculaneum as a representative case of study

Bibliographic Data

ID4635551
AuthorsIñaki Vazquez-De La Fuente (0000-0002-7131-4168), Idoia Etxebarria (0000-0003-2556-9917), Ilaria Costantini (0000-0002-9830-3207), Jennifer Huidobro (0000-0001-8302-8583), Marco Veneranda (0000-0002-7185-2791), Nagore Prieto-Taboada, Nagore Prieto‐Taboada (0000-0003-4649-2381), Giuseppe Di Girolami (0000-0002-8265-6964), Aitor Larrañaga (0000-0002-5823-9714), Angela Di Lillo, Alexandre Lillo, Marina Caso (0000-0002-8639-4957), Mario Notomista, Rossella Di Lauro, Kepa Castro (0000-0002-9931-7889), Gorka Arana (0000-0001-7854-855X), J M Madariaga (0000-0002-1685-6335)
Year2025
Volume73
Pages129-138
Publication date2025-05-01
Peer ReviewedYes
Open AccessYes
TypeARTICLE
VenueJournal of Cultural Heritage (JOURNAL)
Journal identifiersISSN: 1296-2074 • E-ISSN: 1778-3674
PublisherElsevier BV (PUBLISHER)
DOI10.1016/j.culher.2025.02.019
OpenAlexW4408595548
LanguageEN
Citations received1
References cited43

Collaboration of PAERCO, HCP, and IBeA research group on conservation studies. • Identification of rotting in Neapolitan Yellow Tuff using non-destructive analyses. • Discovery: saline humidity causes NYT rotting through salt crystallization. • Sodium sulfate identified as a major threat to NYT conservation efforts. • Preventive measures and portable XRF needed for monitoring historic structures. The eruption of Mount Vesuvius in 79 CE buried Herculaneum under volcanic material, preserving its structures and organic materials remarkably well. Today, this site is known as the Archaeological Park of Herculaneum. Unfortunately, exposure to environmental factors has led to the degradation of Neapolitan Yellow Tuff (NYT), a material commonly used in Roman buildings, through a process known as rotting. This study, conducted by the Herculaneum Archaeological Park (PAERCO) and the Herculaneum Conservation Project (HCP) in collaboration with the IBeA research group (Research and Innovation in Analytical Chemistry, University of the Basque Country UPV/EHU), aimed to understand the tuff rotting process. By combining in-situ non-destructive analyses with laboratory investigations, it was determined, that NYT rotting is caused by the capillary ascent of saline-rich ground humidity, leading to internal stress from salt crystallization, with sodium sulphate identified as a critical threat. Furthermore, the analyses indicated that salts chemically react with NYT's minerals, causing the selective loss of its cementing material (zeolites). The study of soil samples revealed that the risk of rotting varies across the park due to differences in salt concentration and composition. These insights will help PAERCO and HCP identify high-risk areas and implement preventive measures, including the use of portable XRF instruments for ongoing monitoring and preservation of the site's historic structures

Archaeology · Art · Geography · Building materials and conservation · Conservation Techniques and Studies · Cultural Heritage Materials Analysis

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    Open Access•Sara Puente-Muñoz, Jennifer Huidobro et al.•Journal of Cultural Heritage•2025

  • Archaeology and conservation at Herculaneum

    Domenico Camardo•Conservation and Management of…•2006

  • The Oxford Handbook of Papyrology

    Roger S Bagnall•The Oxford handbook of papyrology•2011

  • Evaluation of Natural Stone Weathering in Heritage Building by Infrared Thermography

    Open Access•G Pappalardo, Simone Mineo et al.•Heritage•2022

  • The Herculaneum Conservation Project

    Andrew Wallace-Hadrill•Conservation and Management of…•2006

  • Crystallization damage by sodium sulfate

    Open Access•Nicholas Tsui, Robert J Flatt et al.•Journal of Cultural Heritage•2003

  • Metrological definition and evaluation of some mechanical properties of post-medieval Neapolitan yellow tuff masonry

    Open Access•Bruno Calderoni, Giuseppe Cecere et al.•Journal of Cultural Heritage•2010

Unique citing works1
Citations per year1
Citation span2025 - 2025 (1)
Citation velocityrecent
Highly citedNo
Citation typesNeutral: 1

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