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Romano‐egyptian Red Lead Pigment

A Subsidiary Commodity of Spanish Silver Mining and Refinement

Bibliographic Data

ID8352378
AuthorsMarc Walton (0000-0002-4436-3546, Getty Conservation Institute, corresponding author), M S WALTON, Karen Trentelman (0000-0002-2125-6166, Getty Conservation Institute)
Year2009
Volume51
Issue5
Pages845-860
Publication date2009-10-01
Peer ReviewedYes
Open AccessYes
TypeARTICLE
VenueArchaeometry (JOURNAL)
Journal identifiersISSN: 0003-813X • E-ISSN: 1475-4754
PublisherWiley (PUBLISHER • GB)
DOI10.1111/j.1475-4754.2008.00440.x
OpenAlexW1970046178
LanguageEN
Citations received14
References cited24

Samples of red pigment from a group of seven Roman‐period Egyptian mummies, known as red‐shroud mummies, are investigated. Elemental analysis by inductively coupled plasma time‐of‐flight mass spectrometry (ICP–TOFMS) shows that the samples contain mostly Pb (83–92% by weight), along with 0.2–2.0% Sn. All of the samples are found to have similar trace element distributions when normalized to the continental crust, suggesting that they share a common geological origin. Lead isotope ratios are found to match the mixed lead sources typically associated with Rio Tinto, Spain – a site extensively mined for silver during the first century ad . Raman microspectroscopy identifies the major phase of each sample to be red lead (Pb 3 O 4 ) with a minor phase of lead tin oxide (Pb 2 SnO 4 ). Lead tin oxide does not occur naturally, and its incidental occurrence within the sample indicates that the material was heated under oxidative conditions at temperatures in excess of 650°C. In archaeological contexts, the high‐temperature oxidative treatment of lead is typically associated with metallurgical refinement processes such as cupellation. Based on this evidence, it is argued that the pigment was produced out of litharge associated with silver cupellation at the Rio Tinto site

Archaeology · Cassiterite · Geochemistry · Geography · Lead (geology) · Metallurgy · Mineralogy · Pigment · Tin · Trace element · Building materials and conservation · Chemistry · Conservation Techniques and Studies · Cultural Heritage Materials Analysis · Geology · Materials Science · Paleontology

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Unique citing works14
Citations per year0.82
Citation span2009 - 2026 (18)
Citation velocitycurrent
Highly citedNo
Citation typesNeutral: 13

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