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Eighteenth‐Century M eissen Porcelain Reference Data Obtained By Proton‐Beam Analysis ( Pixe–Pige )

Bibliographic Data

ID8353307
AuthorsC Neelmeijer (Institute of Ion Beam Physics and Materials Research Helmholtz‐Zentrum Dresden‐Rossendorf, P.O.B. 510119 D‐01314 Dresden Germany, corresponding author), U Pietsch (Staatliche Kunstsammlungen Dresden, Porzellansammlung, Zwinger 01067 Dresden Germany), Heike Ulbricht (Dresden State Art Collections)
Year2014
Volume56
Issue4
Pages527-540
Publication date2014-08-01
Peer ReviewedYes
Open AccessYes
TypeARTICLE
VenueArchaeometry (JOURNAL)
Journal identifiersISSN: 0003-813X • E-ISSN: 1475-4754
PublisherWiley (PUBLISHER • GB)
DOI10.1111/arcm.12050
OpenAlexW1553156628
LanguageEN
Citations received2
References cited9

Prior to their restoration, the porcelain bodies of broken pieces from 31 authentic M eissen objects of the early 18th century were investigated by proton‐beam analysis. Attention was paid so that the proton beam probed only the bare porcelain paste areas of fractures. Thus, contributions to the measured X ‐ray and γ‐ray spectra from adjacent surface glaze were prevented. The chemical compositions, obtained by simultaneous detection of elements with Z ≥ 13 ( X ‐rays) and lighter elements Z ≤ 14 (γ‐rays), represent rather consistent mixtures of paste ingredients. This result highlights the durable recipes and raw materials used in early M eissen porcelain production in the years 1725–50. Mean concentration values of element oxides, deduced from the detailed measurements, prove suitable for use as a database for M eissen porcelain paste identification. Material authentication of intact objects, without access to the bare porcelain body, is demonstrated by inspection of the white glaze. Unique museum objects are examined in atmosphere and without sampling. A low proton‐beam intensity and a short irradiation time ensure non‐destructive analysis. Simultaneous radiation and backscattered particle detection allow complete composition analysis, using the established ion beam techniques of particle‐induced X ‐ray emission ( PIXE ), particle‐induced gamma‐ray emission ( PIGE ) and Rutherford backscattering spectrometry ( RBS )

Analytical Chemistry (journal) · Beam (structure) · Ceramic · Composite material · Glaze · Ion beam · Ion beam analysis · Irradiation · Mineralogy · Nuclear physics · Optics · Particle (ecology) · Physics · Proton · Archaeology and ancient environmental studies · Chemistry · Cultural Heritage Materials Analysis · Environmental Chemistry · Geology · Materials Science · X-ray Spectroscopy and Fluorescence Analysis

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Unique citing works2
Citations per year0,2
Citation span2016 - 2026 (11)
Citation velocitycurrent
Highly citedNo
Citation typesNeutral: 2

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