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Ftir and Solid‐state 13 C Cp/Mas NMR Spectroscopy of Charred and Non‐charred Solid Organic Residues Preserved in Roman Iron Age Vessels From the Netherlands

Bibliographic Data

ID8354580
AuthorsT F M OUDEMANS (0009-0003-2239-2519, Leiden University), Jaap J Boon (Institute for Atomic and Molecular Physics), Robert E Botto (Argonne National Laboratory)
Year2007
Volume49
Issue3
Pages571-294
Publication date2007-08-01
Peer ReviewedYes
Open AccessYes
TypeARTICLE
VenueArchaeometry (JOURNAL)
Journal identifiersISSN: 0003-813X • E-ISSN: 1475-4754
PublisherWiley (PUBLISHER • GB)
DOI10.1111/j.1475-4754.2007.00321.x
OpenAlexW2023738121
LanguageEN
Citations received16
References cited52

In this study, solid‐state 13 C magnetic resonance spectroscopy using cross‐polarization combined with high‐powered proton decoupling and magic‐angle sample spinning and Fourier transform infrared spectroscopy using a diamond anvil cell, are employed to give information about the organic functional groups present in charred and non‐charred solid organic residues and to give an insight into the degree of condensation of the chars. Residues were preserved in ceramic vessels recovered from the indigenous settlement of Uitgeest–Groot Dorregeest, dating back to the Roman period. In addition, the application of these solid‐state techniques is used for verification of earlier results obtained in analytical pyrolysis studies and to clarify the relationship between the already thermally degraded charred residues and the controlled heating fragmentation taking place during analytical pyrolysis and direct temperature‐resolved mass spectrometry

Analytical Chemistry (journal) · Elemental analysis · Fourier transform infrared spectroscopy · Infrared spectroscopy · Magic angle spinning · Mass spectrometry · Mineralogy · Nuclear magnetic resonance · Nuclear magnetic resonance spectroscopy · Pyrolysis · Solid-state · Solid-state nuclear magnetic resonance · Archaeology and ancient environmental studies · Chemical Engineering · Chemistry · Cultural Heritage Materials Analysis · Image Processing and 3D Reconstruction · Materials Science · Organic Chemistry · Spectroscopy

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Unique citing works16
Citations per year0,89
Citation span2008 - 2026 (19)
Citation velocitycurrent
Highly citedNo
Citation typesNeutral: 15
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