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Rapid 14 C Analysis of Dissolved Organic Carbon in Non-Saline Waters

Bibliographic Data

ID9245283
AuthorsSusan Q Lang, Cameron P McIntyre (0000-0001-8517-9836), Stefano M Bernasconi (0000-0001-7672-8856), Gretchen L Früh-Green, Britta M Voss, Timothy I Eglinton (0000-0001-5060-2155), Lukas Wacker (0000-0002-8215-2678)
Year2016
Volume58
Issue3
Pages505-515
Publication date2016-09-01
Open AccessYes
TypeARTICLE
VenueRadiocarbon (JOURNAL)
Journal identifiersISSN: 0033-8222 • E-ISSN: 1945-5755
PublisherCambridge University Press (CUP) (PUBLISHER)
DOI10.1017/rdc.2016.17
OpenAlexW2466379120
LanguageEN
Citations received11
References cited29

The radiocarbon content of dissolved organic carbon (DOC) in rivers, lakes, and other non-saline waters can provide valuable information on carbon cycling dynamics in the environment. DOC is typically prepared for 14 C analysis by accelerator mass spectrometry (AMS) either by ultraviolet (UV) oxidation or by freeze-drying and sealed tube combustion. We present here a new method for the rapid analysis of 14 C of DOC using wet chemical oxidation (WCO) and automated headspace sampling of CO 2 . The approach is an adaption of recently developed methods using aqueous persulfate oxidant to determine the δ 13 C of DOC in non-saline water samples and the 14 C content of volatile organic acids. One advantage of the current method over UV oxidation is higher throughput: 22 samples and 10 processing standards can be prepared in one day and analyzed in a second day, allowing a full suite of 14 C processing standards and blanks to be run in conjunction with samples. A second advantage is that there is less potential for cross-contamination between samples

Accelerator mass spectrometry · Aqueous solution · Carbon fibers · Chromatography · Contamination · Dissolved organic carbon · Mass spectrometry · Total organic carbon · Chemistry · Environmental Science · Groundwater and Isotope Geochemistry · Isotope Analysis in Ecology · Marine and coastal ecosystems · Materials Science · Environmental Chemistry

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Citations per year1.1
Citation span2016 - 2025 (10)
Highly citedNo

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