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Investigation of the foil structure and corrosion mechanisms of modern Zwischgold using advanced analysis techniques

Bibliographic Data

ID4722148
AuthorsQing Wu (0000-0002-8716-7342), Karolina Soppa (0000-0002-5838-5391, Bern University of Applied Sciences), Nadim Scherrer, Nadim C Scherrer (0000-0002-6576-885X, Bern University of Applied Sciences), Benjamin Watts (0000-0003-2330-2338, Paul Scherrer Institute), Tadahiro Yokosawa (0000-0001-8785-7493, Friedrich-Alexander-Universität Erlangen-Nürnberg), Laetitia Bernard (0000-0002-7057-6182, Swiss Federal Laboratories for Materials Science and Technology), Tohru Araki (0000-0002-2689-4642, Diamond Light Source), M Döbeli (0000-0001-6839-7698, ETH Zurich), Markus Meyer, Markus R Meyer (0000-0003-4377-6784, Friedrich-Alexander-Universität Erlangen-Nürnberg), Erdmann Spiecker (0000-0002-2723-5227, Friedrich-Alexander-Universität Erlangen-Nürnberg), Rainer H Fink, R Fink (0000-0002-6122-4951, Friedrich-Alexander-Universität Erlangen-Nürnberg)
Year2018
Volume31
Pages122-132
Publication date2018-05-01
Peer ReviewedYes
Open AccessYes
TypeARTICLE
VenueJournal of Cultural Heritage (JOURNAL)
Journal identifiersISSN: 1296-2074 • E-ISSN: 1778-3674
PublisherElsevier BV (PUBLISHER)
DOI10.1016/j.culher.2017.12.005
OpenAlexW2781670954
LanguageEN
Citations received3
References cited11

Zwischgold is a two-sided metal foil made by adhering a gold leaf over a silver leaf to present a gold surface while using less gold than gold foils. Corroded Zwischgold surfaces appear dark, accompanied by gloss loss and possible mechanical stability issues. Zwischgold applied artefacts are commonly found in museums and churches across Europe and they currently face an uncertain future as conservators have little knowledge to base conservation treatments on. We present a comprehensive material analysis of Zwischgold models through advanced characterization techniques including focused ion beam coupled with scanning electron microscopy (FIB-SEM), transmission electron microscopy (TEM), scanning transmission X-ray microscopy (STXM), time-of-flight secondary ion mass spectrometry (TOF-SIMS) and Rutherford backscattering spectrometry (RBS). Complementary information on the foil thickness, sharpness of the gold-silver interface, gold purity, and the formation as well as distribution of corrosion products on Zwischgold models have been obtained, representing a starting point for understanding the morphology and the long-term chemistry of Zwischgold artefacts

Composite material · Corrosion · Focused ion beam · FOIL method · Ion · Mass spectrometry · Metallurgy · Nanotechnology · Rutherford backscattering spectrometry · Scanning electron microscope · Scanning transmission electron microscopy · Secondary ion mass spectrometry · Thin film · Transmission electron microscopy · Chemistry · Conservation Techniques and Studies · Corrosion Behavior and Inhibition · Cultural Heritage Materials Analysis · Materials Science

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Unique citing works3
Citations per year0,5
Citation span2020 - 2023 (4)
Citation velocityhistorical
Highly citedNo
Citation typesNeutral: 3

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