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Revealing ancient gold parting with silver and copper isotopes

Implications From Cementation Experiments and for the Analysis of Gold Artefacts

Bibliographic Data

ID5410075
AuthorsDan Berger (0000-0001-6214-2264, Curt Engelhorn Centre Archaeometry, corresponding author), Michael Brauns (0000-0002-4551-6882, Curt Engelhorn Centre Archaeometry), Gerhard Brügmann (0000-0002-9904-0445, Curt Engelhorn Centre Archaeometry), Ernst Pernicka (0000-0003-4746-9239, Curt Engelhorn Centre Archaeometry), Nicole Lockhoff (Curt Engelhorn Centre Archaeometry)
Year2021
Volume13
Issue9
Publication date2021-09-01
Open AccessYes
TypeARTICLE
VenueArchaeological and Anthropological Sciences (JOURNAL)
Journal identifiersISSN: 1866-9557 • E-ISSN: 1866-9565
PublisherSpringer Science and Business Media LLC (PUBLISHER)
DOI10.1007/s12520-021-01369-2
OpenAlexW3198918582
LanguageEN
Citations received4
References cited42

Gold parting enabled the production of very pure gold for various purposes from the sixth century BC onwards, but analytical proof of this pyrotechnical process is difficult. We describe a new analytical approach for the identification of purified gold combining silver and copper isotopic with trace element analyses. Parting experiments were performed with gold-silver-copper alloys using the classical salt cementation process to investigate potential silver and copper isotope fractionation and changes in trace element concentrations. In addition, we provide the first comprehensive dataset of silver isotope ratios of archaeological gold objects from the Mediterranean and Central Europe to test whether or not gold refining can be identified on the basis of isotope systematics. The results show that very heavy silver and copper isotopic compositions are clear evidence for parted gold, but that the application of copper isotopes might be limited

Cementation (geology · Copper · Fractionation · Geochemistry · Isotope · Isotope fractionation · Metallurgy · Mineralogy · Trace element · Archaeology and ancient environmental studies · Chemistry · Cultural Heritage Materials Analysis · Materials Science · Mineralogy and Gemology Studies · Geology

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Citations per year2
Citation span2024 - 2026 (3)
Highly citedNo

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