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Micro‐raman Spectroscopy Characterization of Della Robbia Glazes

Bibliographic Data

ID8352853
AuthorsMariana Sendova (0000-0002-2040-6791, New College of Florida), V ZHELYASKOV (New College of Florida), M SCALERA (Ringling College of Art and Design), C GULLIFORD (New College of Florida)
Year2007
Volume49
Issue4
Pages655-664
Publication date2007-11-01
Open AccessYes
TypeARTICLE
VenueArchaeometry (JOURNAL)
Journal identifiersISSN: 0003-813X • E-ISSN: 1475-4754
PublisherWiley (PUBLISHER • GB)
DOI10.1111/j.1475-4754.2007.00326.x
OpenAlexW2074380836
LanguageEN
Citations received2
References cited19

Micro‐Raman spectroscopy and the laser‐induced transformation technique were used for systematic study of five coloured glazes on Saint John the Baptist (29 inch tondo), a majolica terracotta relief attributed to Luca Della Robbia and on permanent exhibit in The John and Mable Ringling Museum of Art. We suggest that ions in a lead silicate matrix, called ‘lead ultramarine’, could contribute to the famous Della Robbia blue colour, in addition to the effect of Co atoms as suggested previously by Pappalardo et al. (2004 ). The original yellow glaze contains lead(II) antimonate. The green is a mixture of the yellow and blue pigments, the brown contains hematite, and the white glaze contains tin dioxide as an opacifier. The use of lead oxide as a main fluxing agent is confirmed by laser‐induced micro‐crystallization

Antimonate · Antimony · Cassiterite · Ceramic · Characterization (materials science) · Cinnabar · Glaze · Hematite · Metallurgy · Mineralogy · Nanotechnology · Optics · Raman spectroscopy · Tin · Building materials and conservation · Chemistry · Conservation Techniques and Studies · Cultural Heritage Materials Analysis · Materials Science

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    Open Access•Ian M Bell, Robin J H Clark et al.•Spectrochimica Acta Part A:…•1997

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Citations per year0.11
Citation span2008 - 2014 (7)
Highly citedNo

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