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Molecular Sieves in 14 CO 2 Sampling and Handling

Bibliographic Data

ID9241891
AuthorsV Palonen, Markku Oinonen (0000-0002-0881-7643)
Year2013
Volume55
Issue2
Pages416-420
Publication date2013-01-01
Open AccessYes
TypeARTICLE
VenueRadiocarbon (JOURNAL)
Journal identifiersISSN: 0033-8222 • E-ISSN: 1945-5755
PublisherCambridge University Press (CUP) (PUBLISHER)
DOI10.1017/s0033822200057544
OpenAlexW4241255591
LanguageEN
Citations received1
References cited6

Molecular sieves are a promising way to sample and manipulate gaseous samples for radiocarbon analyses. Molecular sieve material can adsorb CO 2 selectively, enabling sampling of CO 2 from large air volumes in a small amount of adsorbent. The sieve material can be regenerated via heating and reused without removing the sieve material from its container. This results in ease of use and reduced risks of atmospheric contamination. Because sieve container volume is small and can be filled with synthetic air or nitrogen, it does not introduce underpressure to the system under study. Hence, sieves are suitable for many different experimental setups, from collection of CO 2 from small soil chambers to atmospheric CO 2 collection. The most common sieve material in use for sampling CO 2 is the 13X zeolite. For environmental measurements starting this year, we have studied the properties of 13X zeolites in more detail. For reliable 14 CO 2 sampling, there are several caveats that should and can be avoided. In this contribution, we discuss these caveats and solutions to optimize the molecular sieve sampling process

Adsorption · Mineralogy · Molecular sieve · Optics · Physics · Zeolite · Archaeology and ancient environmental studies · Chemistry · Environmental Science · Geology and Paleoclimatology Research · Isotope Analysis in Ecology · Materials Science · Mathematics · Catalysis · Environmental Chemistry · Organic Chemistry

  • Seasonal and Diurnal Variations in Atmospheric and Soil Air 14 CO 2 in a Boreal Scots Pine Forest

    Open Access•Vesa Palonen, J Pumpanen et al.•Radiocarbon•2018

  • Carbon Dioxide Capture Using a Zeolite Molecular Sieve Sampling System for Isotopic Studies ( 13 C and 14 C) of Respiration

    Open Access•S M L Hardie, M H Garnett et al.•Radiocarbon•2005

  • Processing of CO2 Samples Collected Using Zeolite Molecular Sieve for 14C Analysis at the Nerc Radiocarbon Facility (East Kilbride, UK)

    Mark Garnett•Radiocarbon•2013

Citations per year0.13
Citation span2018 - 2018 (1)
Highly citedNo

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