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Radiocarbon and Stable Carbon Analysis of Dissolved Methane and Carbon Dioxide from the Profile of a Raised Peat Bog

Bibliographic Data

ID9242009
AuthorsM H Garnett (0000-0001-6486-2126), S M L Hardie, C Murray (0000-0003-1216-2800)
Year2011
Volume53
Issue1
Pages71-83
Publication date2011-01-01
Open AccessYes
TypeARTICLE
VenueRadiocarbon (JOURNAL)
Journal identifiersISSN: 0033-8222 • E-ISSN: 1945-5755
PublisherCambridge University Press (CUP) (PUBLISHER)
DOI10.1017/s0033822200034366
OpenAlexW314508890
LanguageEN
Citations received5
References cited24

We developed and tested a new method to separate CO 2 and CH 4 from bulk gas samples for radiocarbon and stable-carbon analysis that utilizes a zeolite molecular sieve. To validate the technique, tests were performed using a suite of standard gases, composed of CO 2 and CH 4 of distinctly different isotopic composition. We employed the method to investigate the carbon isotopic composition of samples of dissolved CO 2 and CH 4 collected in situ from the near surface to deep layers of an ombrotrophic raised peat bog. Results showed that the age of both the CO 2 and CH 4 components of the dissolved gases increased with depth from ≃0–300 BP at 0.25 m to ≃4000 BP at 4 m. CH 4 was mainly similar or slightly older in age compared to CO 2 , with the greatest difference in ages occurring at 1 m depth where CH 4 was older by 430–615 yr. The δ 13 C values of CO 2 increased with depth from −12.4‰ and −8.0‰ at 0.25 m to +6.9‰ and +8.3‰ at 4 m, whereas the δ 13 C of CH 4 stayed in the range −58.4‰ to −70.6‰. The 14 C results from the deepest layers are consistent with a similar source for both gases. 14 C ages for the CO 2 component were younger compared to CH 4 , within the shallower depths of the peat bog (≤1 m) and demonstrate the incorporation of acrotelm-derived respired CO 2 into the catotelm

Archaeology · Bog · Carbon dioxide · Carbon fibers · Dissolved organic carbon · Isotopes of carbon · Methane · Mineralogy · Ombrotrophic · Peat · Radiocarbon dating · Total organic carbon · Chemistry · Coastal wetland ecosystem dynamics · Geology and Paleoclimatology Research · Materials Science · Peatlands and Wetlands Ecology · Environmental Chemistry · Geology

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    Open Access•Satabdi Misra, Sneha Kashyap et al.•Radiocarbon•2024

  • C Measurement of Samples for Environmental Science Applications at the National Environmental Isotope Facility (Neif) Radiocarbon Laboratory, Suerc, Uk

    Open Access•Philippa Ascough, N Bompard et al.•Radiocarbon•2024

  • Compound-Specific Radiocarbon Analysis of Atmospheric Methane

    Open Access•C Espic, M Liechti et al.•Radiocarbon•2019

  • Radiocarbon Analysis of Methane at the Nerc Radiocarbon Facility (East Kilbride)

    Open Access•M H Garnett, C Murray et al.•Radiocarbon•2019

  • Time-Integrated Collection of Co 2 for 14 C Analysis From Soils

    Open Access•Shawn Pedron, X Xu et al.•Radiocarbon•2021

  • Carbon Dioxide Capture Using a Zeolite Molecular Sieve Sampling System for Isotopic Studies ( 13 C and 14 C) of Respiration

    Open Access•S M L Hardie, M H Garnett et al.•Radiocarbon•2005

  • Carbon Isotopic Composition of Deep Carbon Gases in an Ombrogenous Peatland, Northwestern Ontario, Canada

    Open Access•Ramon Aravena, B G Warner et al.•Radiocarbon•1993

  • Discussion Reporting of 14 C Data

    Open Access•Minze Stuiver, Henry A Polach•Radiocarbon•1977

  • Report of the Tiri Workshop, Saturday 13 August 1994

    Open Access•Steinar Gulliksen, Marian Scott•Radiocarbon•1995

Citations per year0.71
Citation span2019 - 2024 (6)
Highly citedNo

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