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Compound-Specific Radiocarbon, Stable Carbon Isotope and Biomarker Analysis of Mixed Marine/Terrestrial Lipids Preserved in Archaeological Pottery Vessels

Bibliographic Data

ID9242968
AuthorsEmmanuelle Casanova (0000-0003-1417-3060), Timothy D J Knowles (0000-0003-4871-5542), Candice Ford, Lucy J E Cramp, Niall Sharples, R P Evershed (0000-0002-9483-2750)
Year2020
Volume62
Issue6
Pages1679-1697
Publication date2020-12-01
Open AccessYes
TypeARTICLE
VenueRadiocarbon (JOURNAL)
Journal identifiersISSN: 0033-8222 • E-ISSN: 1945-5755
PublisherCambridge University Press (CUP) (PUBLISHER)
DOI10.1017/rdc.2020.11
OpenAlexW3010647718
LanguageEN
Citations received14
References cited37

At archaeological sites located on islands or near the coast, the potential exists for lipid extracts of potsherds to contain fatty acids (FA) from both aquatic and terrestrial organisms, meaning that consideration must be given to marine reservoir effects (MRE) in radiocarbon ( 14 C) analyses. Here we studied the site of Bornais (Outer Hebrides, UK) where a local MRE, ΔR of –65 ± 45 yr was determined through the paired 14 C determinations of terrestrial and marine faunal bones. Lipid analysis of 49 potsherds, revealed aquatic biomarkers in 45% of the vessels, and δ 13 C values of C 16:0 and C 18:0 FAs revealed ruminant and marine product mixing for 71% of the vessels. Compound-specific 14 C analysis (CSRA) of FAs yielded intermediate 14 C ages between those of terrestrial and marine bones from the same contexts, confirming an MRE existed. A database containing δ 13 C values for FAs from reference terrestrial and marine organisms provided endmembers for calculating the percentage marine-derived C ( % marine ) in FAs. We show that lipid 14 C dates can be corrected using determined % marine and ΔR values, such that pottery vessels from coastal locations can be 14 C dated by CSRA of FAs

Archaeology · Biology · Geography · Isotope analysis · Isotopes of carbon · Pottery · Radiocarbon dating · Total organic carbon · Archaeology and ancient environmental studies · Isotope Analysis in Ecology · Pacific and Southeast Asian Studies · Ecology · Geology · Oceanography · Paleontology

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Citations per year2.8
Citation span2021 - 2026 (6)
Highly citedNo

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