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Marine Organic Carbon and Radiocarbon—present and Future Challenges

Bibliographic Data

ID9243195
AuthorsEllen R M Druffel (0000-0002-7139-1075), Steven R Beaupré (0000-0001-6964-1058), Hendrik Grotheer (0000-0003-0207-3767), Christian B Lewis, Ann P McNichol (0000-0002-9895-3912), Gesine Mollenhauer (0000-0001-5138-564X), Brett D Walker (0000-0003-4904-826X)
Year2022
Volume64
Issue4
Pages705-721
Publication date2022-08-01
Peer ReviewedYes
Open AccessYes
TypeARTICLE
VenueRadiocarbon (JOURNAL)
Journal identifiersISSN: 0033-8222 • E-ISSN: 1945-5755
PublisherCambridge University Press (CUP) (PUBLISHER)
DOI10.1017/rdc.2021.105
OpenAlexW4210434773
LanguageEN
Citations received1
References cited109

We discuss present and developing techniques for studying radiocarbon in marine organic carbon (C). Bulk DOC (dissolved organic C) Δ 14 C measurements reveal information about the cycling time and sources of DOC in the ocean, yet they are time consuming and need to be streamlined. To further elucidate the cycling of DOC, various fractions have been separated from bulk DOC, through solid phase extraction of DOC, and ultrafiltration of high and low molecular weight DOC. Research using 14 C of DOC and particulate organic C separated into organic fractions revealed that the acid insoluble fraction is similar in 14 C signature to that of the lipid fraction. Plans for utilizing this methodology are described. Studies using compound specific radiocarbon analyses to study the origin of biomarkers in the marine environment are reviewed and plans for the future are outlined. Development of ramped pyrolysis oxidation methods are discussed and scientific questions addressed. A modified elemental analysis (EA) combustion reactor is described that allows high particulate organic C sample throughput by direct coupling with the MIniCArbonDAtingSystem

Accelerator mass spectrometry · Carbon cycle · Carbon fibers · Chromatography · Dissolved organic carbon · Organic matter · Particulates · Pyrolysis · Radiocarbon dating · Total organic carbon · Ultrafiltration (renal) · Chemistry · Environmental Science · Isotope Analysis in Ecology · Marine and coastal ecosystems · Materials Science · Ocean Acidification Effects and Responses · Ecology · Environmental Chemistry · Geology · Organic Chemistry

  • Radiocarbon measurements of dissolved inorganic carbon (DIC) in sediment porewater and seawater at AWI Micadas

    Open Access•Hendrik Grotheer, Jens S Hammes et al.•Radiocarbon•2025

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    Open Access•Matthew A Pendergraft, Zeynep Dincer et al.•Environmental Research Letters•2013

  • Sediment chronology in Antarctic deglacial sediments

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    Open Access•Guaciara M Santos, John R Southon et al.•Radiocarbon•2010

  • Assessing the Blank Carbon Contribution, Isotope Mass Balance, and Kinetic Isotope Fractionation of the Ramped Pyrolysis/Oxidation Instrument at Nosams

    Open Access•Jordon D Hemingway, Valier V Galy et al.•Radiocarbon•2017

  • UV Photochemical Oxidation and Extraction of Marine Dissolved Organic Carbon at UC Irvine

    Open Access•Brett D Walker, Steven R Beaupré et al.•Radiocarbon•2019

  • Improving Antarctic Sediment 14 C Dating Using Ramped Pyrolysis

    Open Access•Brad E Rosenheim, Jennifer A Santoro et al.•Radiocarbon•2013

  • Global Ocean Radiocarbon Programs

    Open Access•Ann P McNichol, Robert M Key et al.•Radiocarbon•2022

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  • C Blank Assessment in Small-Scale Compound-Specific Radiocarbon Analysis of Lipid Biomarkers and Lignin Phenols

    Open Access•Shuwen Sun, Vera D Meyer et al.•Radiocarbon•2020

Unique citing works1
Citations per year1
Citation span2025 - 2025 (1)
Citation velocityrecent
Highly citedNo
Citation typesNeutral: 1

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