Electron Spin Resonance Study of Paper Samples Dating From the Fifteenth to the Eighteenth Century
Bibliographic Data
| ID | 8354549 |
|---|---|
| Authors | Donato Attanasio (Istituto di Metodologie Chimiche), Donatella Capitani (0000-0003-2392-0187, Istituto di Metodologie Chimiche), Carlo Federici (0000-0002-0309-4669), Anna Laura Segre (Istituto di Metodologie Chimiche) |
| Year | 1995 |
| Volume | 37 |
| Issue | 2 |
| Pages | 377-384 |
| Publication date | 1995-08-01 |
| Peer Reviewed | Yes |
| Open Access | Yes |
| Type | ARTICLE |
| Venue | Archaeometry (JOURNAL) |
| Journal identifiers | ISSN: 0003-813X • E-ISSN: 1475-4754 |
| Publisher | Wiley (PUBLISHER • GB) |
| DOI | 10.1111/j.1475-4754.1995.tb00750.x |
| OpenAlex | W2125888269 |
| Language | EN |
| Citations received | 4 |
| References cited | 12 |
Electron paramagnetic resonance spectroscopy is used to detect paramagnetic impurities in differently degraded antique sheets of unprinted paper. Impurities consist primarily of transition metal ions (Fe 3+ , Mn 2+ , Cu 2+ ) present in different environments and symmetries. Organic radicals, common in modern, wood pulp paper, are absent in these antique samples made from rags. Fe 3+ is the largest impurity (from 300 to 700 ppm). Mn 2+ is also present but its concentration does not exceed 50ppm. Cu 2+ has been detected in about one‐third of the samples. Coupled with nuclear magnetic resonance data, these results describe degradation as an hydrolytic process leading to a net increase of amorphous cellulose and to a decrease of bound water. Copper and rhombic iron appear to act as efficient degradation catalysts, whereas the presence of octahedral iron is almost irrelevant
Amorphous solid · Analytical Chemistry (journal) · Antique · Cellulose · Copper · Crystallography · Electron paramagnetic resonance · Impurity · Ion · Nuclear magnetic resonance · Octahedron · Paramagnetism · Physics · Radical · Building materials and conservation · Catalysis · Chemistry · Condensed Matter Physics · Cultural Heritage Materials Analysis · Materials Science · Organic Chemistry · X-ray Spectroscopy and Fluorescence Analysis
An Introduction to the Electron Paramagnetic Resonance Spectral Library of Pigments
Mapping Pigments in a Painting with Low Frequency Electron Paramagnetic Resonance Spectroscopy
Characterization of Pigment and Binder in Badly Conserved Illuminations of a 15th‐Century Manuscript
Archaeometry and Museums
| Unique citing works | 4 |
|---|---|
| Citations per year | 0,22 |
| Citation span | 2008 - 2022 (15) |
| Citation velocity | historical |
| Highly cited | No |
| Citation types | Neutral: 4 |